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OBTAINING CLINKERLESS CEMENTS THROUGH THE SYNTHESIS OF BASIC SOLUTIONS OF SODIUM SILICATE FROM SILICA-CONTAINING ROCKS

https://doi.org/10.21822/2073-6185-2019-46-3-149-158

Abstract

 Objectives The creation of clinkerless cements that do not require high-temperature processing and significant natural resources, at the same time as exhibiting good technical parameters, seems to be an important research task. Cements of alkaline instillation, in which alkaline metals play an active role, are capable of interacting with minerals of aluminosilicate nature forming strong and insoluble compounds.

Methods Concrete composites from binding substances activated by alkaline were developed on the basis of Russian and foreign experience of using cinder slag composites in construction.

Results In this work, energy-dispersion microanalysis of the developed clinkerless compositions based on alkaline silicate sodium solutions from silica-containing rocks was carried out.

Conclusion Formulations of clinkerless cements based on high-dispersal powders of different natures mixed by the alkaline solution obtained using the wet technique at temperatures of up to 95 °C and atmospheric pressure are proposed. This technology will expand the use of alkaline cements, thus leading to the development of concrete having desired properties. 

About the Authors

M. Sh. Salamanova
Academician M.D. Millionshchikov Grozny State Oil Technical University
Russian Federation

Cand. Sci. (Technical). Assoc. Prof., Department of Construction Technology

100 Isaev Ave., Grozny 364051



S.-A. Yu. Murtazaev
Academician M.D. Millionshchikov Grozny State Oil Technical University; Kh. Ibragimov Complex Institute of the Russian Academy of Sciences
Russian Federation

Dr. Sci. (Technical). Prof. ,Head of the Department of Construction Technology

100 Isaev Ave., Grozny 364051; 21а Stropromyslovsky Hig., Grozny 364021



Z. H. Ismailova
Academician M.D. Millionshchikov Grozny State Oil Technical University
Russian Federation

Cand. Sci. (Technical). Assoc. Prof., Department of Construction Technology

100 Isaev Ave., Grozny 364051



R. G. Bisultanov
Academician M.D. Millionshchikov Grozny State Oil Technical University
Russian Federation

Cand. Sci. (Technical). Assoc. Prof., Department of Building Structures

100 Isaev Ave., Grozny 364051



References

1. Dietz A, Ramroth H, Urban T, Ahrens W, Becher H (2004) Exposure to cement dust, related occupational groups and laryngeal cancer risk: Results of a population based case-control study. Int J Cancer, 108.

2. Al-Neaimi YI, Gomes J, Lloyd OL (2001) Respiratory illnesses and ventilator function among workers at a cement Factory in a rapidly developing country. Occup Med (Lond), 51, 367-73.

3. Murtazayev S.-A.YU., Salamanova M.SH., Vatayev U.V. Tsementnaya promyshlennost' Chechenskoy respubliki / Vestnik Akademii Nauk Chechenskoy respubliki № 1 (22) , Groznyy 2014, S. 109-114. [Murtazaev S.-A.Yu., Salamanova M.Sh., Vataev U.V. The cement industry of the Chechen Republic / Bulletin of the Academy of Sciences of the Chechen Republic No. 1 (22), Grozny 2014, pp 109-114. (In Russ)]

4. Nesvetaev G., Koryanova Y., Zhilnikova T. On effect of superplasticizers and mineral additives on shrink-age of hardened cement paste and concrete // In the collection: MATEC Web of Conferences 27. Ser. "27th R-S-P Seminar, Theoretical Foundation of Civil Engineering (27RSP), TFoCE 2018" 2018.P. 04018.

5. Stelmakh S.A., Nazhuev M.P., Shcherban E.M., Yanovskaya A.V., Cherpakov A.V. Selection of the composition for centrifuged concrete, types of centrifuges and compaction modes of concrete mixtures // Physics and Mechanics of New Materials and Their Applications (PHENMA 2018) Abstracts & Sched-ule. Edited by Yun-Hae Kim, I.A. Parinov, S.-H. Chang. 2018.S. 337.

6. Shuisky A., Stelmakh S., Shcherban E., Torlina E. Recipe-technological aspects of improving the properties of non-autoclaved aerated concrete // MATEC Web of Conferences Ser. "International Conference on Modern Trends in Manufacturing Technologies and Equipment, ICMTMTE 2017" 2017.P. 05011.

7. Soldatov A.A., Sariyev I.V., Zharov M.A., Abduraimova M.A. Stroitel'nyye materialy na osnove zhidkogo stekla // V sbornike: Aktual'nyye problemy stroitel'stva, transporta, mashinostroyeniya i tekhnosfernoy bezopasnosti Materialy IV-y yezhegodnoy nauchno-prakticheskoy konferentsii Severo-Kavkazskogo federal'nogo universiteta. N.I. Stoyanov (otvetstvennyy redaktor). 2016. – S. – 192-195. [Soldatov A.A., Sariev I.V., Zharov M.A., Abduraimova M.A. Building materials based on liquid glass // In the collection: Actual problems of construction, transport, engineering and technosphere safety Materials of the IVth annual scientific and practical conference of the North Caucasus Federal University. N.I. Stoyanov (executive editor). 2016 . pp. 192-195. (In Russ)]

8. Murtazayev S-A.YU., Salamanova M.SH., Saydumov M.S., Alaskhanov A.KH. Issledovaniye svoystv beto-nov na besklinkernykh vyazhushchikh // Perspektivy razvitiya toplivno-energicheskogo kompleksa i so-vremennoye sostoyaniye neftegazovogo inzhenernogo obrazovaniya v Rossii, posvyashchennaya 105-letiyu M. D. Millionshchikova: materialy Vserossiyskoy nauchno – prakticheskoy konferentsii 11-12 iyunya 2018 g. – Groznyy: FGBOU VO «GGNTU», 2018. S.392 – 399. [Murtazaev S-A.YU., Salamanova M.Sh., Saidumov M.S., Alashkhanov A.Kh. Study of the properties of concrete on clinkerless binders // Prospects for the development of the fuel and energy complex and the current state of oil and gas engineering education in Russia, dedicated to the 105th anniversary of M.D. Millionshchikov: materials of the AllRussian Scientific and Practical Conference June 11-12, 2018 Terrible: FSBEI HE "GSTU", 2018. pp.392 - 399. (In Russ)]

9. Salamanova M.Sh., Murtazayev S. Yu., Ismailova ZH The Use of Highly Active Additives for the Produc-tion of Clinkerless Binders // Proceedings of the International Symposium “Engineering and Earth Scienc-es: Applied and Fundamental Research” (ISEES 2018) ISSN Part of series: AER, ISSN: 2352-5401, volume: 177 ISBN 978-94-6252-637-2, pp. 355-358.

10. Salamanova M.Sh., Murtazayev S. Yu. Clinker-free binders based on finely dispersed mineral components // 20. Internationale Baustofftagung, Tagungsbericht. 12-14 september 2018, Bauhaus-Universitdt Weimar. Band 1 und 2. - Weimar: 2018. Issue. 2. pp.707-714.

11. Volodchenko, A.A., Lesovik, V.S., Zagorodnjuk, L.H., Volodchenko, A.N. Influence of the inorganic modifier structure on structural composite properties // International Journal of Applied Engineering Re-search. 2015. Volume 10. Issue 19. Pages 40617-40622.

12. Lesovik, V.S., Zagorodnyuk, L.K., Mestnikov, A.E., Kudinova, A.I., Sumskoi, D.A. Designing of mortar compositions on the basis of dry mixes // International Journal of Applied Engineering Research. 2015. Volume 10. Issue 5. Pages 12383-12390.

13. Volodchenko, A.A., Lesovik, V.S., Volodchenko, A.N., Zagorodnjuk, L.H., Pukharenko, Y.V. Composite performance improvement based on non-conventional natural and technogenic raw materials // 2016. International Journal of Pharmacy and Technology 2016.8 (3), p. 18856-18867

14. Davidovitz J. Geopolymer. Chemistry and applications. Saint-Quentin: Institute Geopolymer. 2008 / - 592 pp.

15. Geopolymer technology: The current state of the art // P. Duxson, A. Fernandez, J. Provis / J. Mater. Sci. 2007.–V. 42. P.2917-2933.

16. Murtazayev S.-A.YU. Vliyaniye aktivnykh tsentrov poverkhnosti na reaktsionnuyu sposobnost' mine-ral'nykh dobavok / S.-A.YU. Murtazayev, M.SH. Salamanova, M.S. Saydumov, Z.KH. Ismailova // Nauch-nyy zhurnal «Sovremennaya nauka i innovatsii» (Stavropol' – Pyatigorsk). – 2017. - №2 (18). -S.168-175. [Murtazaev S.-A. Yu. The effect of active surface centers on the reactivity of mineral additives / S.-A. Yu. Murtazaev, M.Sh. Salamanova, M.S. Saidumov, Z.Kh. Ismailova // Scientific journal "Modern Science and Innovation" (Stavropol - Pyatigorsk). 2017. No. 2 (18). pp.168175. (In Russ)]

17. S.-A.YU. Murtazayev, M.SH. Salamanova Perspektivy ispol'zovaniya termoaktivirovannogo syr'ya alyumosilikatnoy prirody // Privolzhskiy nauchnyy zhurnal. – 2018. – №2 (T.46).– S. 65 –70. [ S.-A.Y. Murtazaev, M.Sh. Salamanova Prospects for the use of thermally activated raw materials of aluminosilicate nature // Volga Scientific Journal. 2018. No. 2 (T.46) pp. 65 –70. (In Russ)]

18. Martschuk V. Untersuchungen zurn Frost-Tausalz-Widerstaud von Mochleistungsbetonen / V. Martschuk, T. Stark // Thesis: Wiss. Z.Bauhaus -Univ. Weirnar. 1998. V.44. No1-2. pp. 92-103.

19. Larbi, J.A. Effect of water-cement ratio, quantity and fineness of sand on the evolution of lime in set port-land cement systems / J.A. Larbi, J.M. Bijen // Cem. and concr. Res. - 1990. Vol.20. No. 5. pp. 783-794.

20. Kozhuhova N.I., Zhernovskiy I.V., Osadchaya M.S., Strokova V.V., Tchizhov R.V. Revisiting a selection of natural and technogenic raw materials for geopolym


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For citations:


Salamanova M.Sh., Murtazaev S.Yu., Ismailova Z.H., Bisultanov R.G. OBTAINING CLINKERLESS CEMENTS THROUGH THE SYNTHESIS OF BASIC SOLUTIONS OF SODIUM SILICATE FROM SILICA-CONTAINING ROCKS. Herald of Dagestan State Technical University. Technical Sciences. 2019;46(3):149-158. (In Russ.) https://doi.org/10.21822/2073-6185-2019-46-3-149-158

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