SYNTHESIS OF OSMIUM COMPLEXES ON THE BASE OF NEW POLYMERS CONTAINING AMINE AND CARBOXYLIC FUNCTIONAL GROUPS
https://doi.org/10.21822/2073-6185-2013-29-2-105-110
Abstract
Osmium complexes by interaction osmium bipyridyl chloride (Os(bipy)2Cl2) and dimmethylbipyridil chloride (Os(dimebipy)2Cl2) with a number of synthesised polymers on the base of 1-(3-aminepropyl)-imidazole, methylmethacrylate, acrylic acid and butylacrylate have been obtained. It have been shown that osmium complexes of the obtained polymers with bipyridyl chloride and dimmethylbipyridil chloride could be used as effective mediators for reagentless amperometric biosensors.
About the Author
Yu. M. Sultanov
Дагестанский государственный технический университет
Russian Federation
Russian Federation
References
1. Degani Y., Heller A. // J. Am. Chem. Soc. 1989, v. 111, p.2357-2358.
2. Heller A. // Accounts of Chemical Research, 1990, v. 23, p.128-134.
3. Kashiwagi Y., Pan Q., Yanagisawa Y. et al. // Denki Kagaku. 1994, v.62, p.1240-1246.
4. Badia A., Carlini R., Fernandez A. et al. // J. Am. Chem. Soc. 1993, v. 115, p. 7053-7060.
5. Battaglini F., Barlett P.N., Wang J.H. // Anal. Chem. 2000, v.72, p.502-509.
6. De Lumley-Woodyear T., Rocca P., Lindsay J. et al. // Anal. Chem. 1995, v.67, p. 1332- 1338.
7. Habermüller K., Ramanavicius A., Laurinavicius V., Schuhmann W. // Electroanalysis, 2000, v.12, p.1383-1389.
Review
For citations:
Sultanov Yu.M. SYNTHESIS OF OSMIUM COMPLEXES ON THE BASE OF NEW POLYMERS CONTAINING AMINE AND CARBOXYLIC FUNCTIONAL GROUPS. Herald of Dagestan State Technical University. Technical Sciences. 2013;29(2):105-110. (In Russ.) https://doi.org/10.21822/2073-6185-2013-29-2-105-110
Views:
560
Email this article 
