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SENSITIVE POTENTIOMETRIC SENSOR TO IONS OF LEAD (II)

https://doi.org/10.21822/2073-6185-2014-32-1-82-86

Abstract

Sensitive potentiometric sensor to ions of lead (II) is made by optimizing the composition of the plasticized membrane. Electrochemical and analytical performance of the electrode are established. The slope of the electrode function is 26,7533 ± 1,09038 mV / dec. The linear range of operation is 0,1- 1 • 10-5 M. The ions of zinc, cadmium, mercury, and to a lesser extent copper can have the
interfering effect of the determination of lead ions. Ions of some alkali and alkaline earth metals.do not interfere with the definition.

About the Authors

K. E. Magomedov
Дагестанский государственный университет
Russian Federation


S. D. Tataeva
Дагестанский государственный университет
Russian Federation


V. S. Goryachaya
Дагестанский государственный университет
Russian Federation


References

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2. S. Y. Kazemi, M. Shamsipur and H. Sharghi, “Lead- Selective Poly(vinyl chloride) Electrodes Based on Some Synthesized Benzo-Substituted MacrocyclicDiamides,” Journal of Hazardous Materials, Vol. 172, 2009, pp. 68-73

3. S. Mathew, L.Rajith, L. A.Lonappan, T. Jos, K. G. Kumar. A lead (II) selective PVC membrane potentiometric sensor based on a tetraazamacrocyclic ligand// Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2013. http://dx.doi.org/10.1007/s10847-013-0285-2.

4. M.F. Mousavi, M.B. Barzegar, S. Sahari. A PVC-based capric acid membrane potentiometric sensor for lead(II) ions// Sensors and Actuators B 73 (2001) 199-204.


Review

For citations:


Magomedov K.E., Tataeva S.D., Goryachaya V.S. SENSITIVE POTENTIOMETRIC SENSOR TO IONS OF LEAD (II). Herald of Dagestan State Technical University. Technical Sciences. 2014;32(1):85-93. (In Russ.) https://doi.org/10.21822/2073-6185-2014-32-1-82-86

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ISSN 2073-6185 (Print)
ISSN 2542-095X (Online)